Relationship between subcellular cadmium distribution in prey and cadmium trophic transfer to a predator   总被引：1，自引：0，他引：1  

William G. Wallace  Glenn R. Lopez 《Estuaries and Coasts》1996,19(4):923-930

We tested the hypothesis that exposure-related alterations in the subcellular Cd distribution in prey relate to changes in Cd absorption by a predator. Oligochaete worms,Limnodrilus hoffmeisteri were exposed for 1 wk or 6 wk to 0.5 μg Cd 1^?1, 47 μg Cd 1^?1, or 140 μg Cd 1^?1 (including¹⁰⁹Cd as a tracer) and relationships between oligochaete subcellular Cd distribution and Cd absorption by a predator, the grass shrimp (Palaemonetes pugio), were determined. Concentration and duration of Cd exposure had direct effects on oligochaete subcellular Cd distribution. Changes in oligochaete subcellular Cd distribution were characterized by increases in both the amount and proportion of Cd bound to the cytosolic fraction. The induction of Cd-binding proteins (e.g., metallothioneins) were suspected to be responsible for these changes. We found 1∶1 relationships between the amount and percentage of Cd in oligochaete cytosol and the amount and percentage of Cd adsorbed by shrimp. These results demonstrate that only metal bound to the soluble fraction of prey is available to higher trophic levels, and that factors influencing subcellular metal distribution in prey will directly alter metal trophic transfer to predators.  相似文献   

Experimental Investigation of Surfactant-Enhanced Dissolution of Residual NAPL in Saturated Soil     

Lizette R. Chevalier  Susan J. Masten  Roger B. Wallace  David C. Wiggert 《Ground Water Monitoring & Remediation》1997,17(4):89-98

Nonaqueous phase liquid (NAPL) is a long-term source of ground water contamination as the pollutant slowly partitions into the air and water phases. The objective of this work was to study the efficacy of aqueous surfactant solution to enhance the dissolution of a residual NAPL below the capillary fringe, hence reducing the time needed for aquifer restoration. An analytical technique was developed to measure the concentration of NAPL in a nonionic surfactant. Soil column experiments simulated conditions in the saturated soil where a NAPL may become trapped as a discontinuous immobile phase. Experimental results indicate that dissolution was a rate-limited process, approaching equilibrium concentrations after 24 hours. The relative permeability of the aqueous phase initially decreased as surfactant was injected, but increased over time as the saturation of residual NAPL was reduced through mass transfer into the surfactant-enhanced aqueous phase. These findings suggest that enhancing the aqueous phase with a nonionic surfactant may significantly enhance the in situ recovery or residual NAPL.  相似文献   

The radiocarbon budget for Mono Lake: an unsolved mystery     

Wallace S. Broecker  Rik Wanninkhof  Guy Mathieu  Tsung-Hung Peng  Scott Stine  Steve Robinson  Andy Herczeg  Minze Stuiver 《Earth and Planetary Science Letters》1988,88(1-2)

Since 1957 the ¹⁴C/C ratio of the dissolved inorganic carbon in Mono Lake has risen by about 60‰. The magnitude of this increase is about four times larger than that expected from the invasion of bomb-produced¹⁴C from the atmosphere. We have eliminated the following explanations: (1) measurement error, (2) an unusually high physical exchange rate for non-reactive gases, (3) inorganic enhancement of the CO₂ exchange rate, and (4) biological enhancement of the CO₂ exchange rate. Clandestine disposal of waste radiocarbon remains a dark-horse explanation.In the course of our investigations we have uncovered evidence for at least one episodic input of radiocarbon-free carbon to the lake over the last 1000 years. We speculate that this injection was related to a hydrothermal event resulting from sublacustrine volcanic activity.  相似文献   

Introduction toelectrical properties of the Earth's mantle     

Wallace H. Campbell 《Pure and Applied Geophysics》1987,125(2-3):193-204

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Heat flow and depth versus age for the Mesozoic northwest Atlantic Ocean: results from the Sohm abyssal plain and implications for the Bermuda Rise     

K.E. Louden  Derek O. Wallace  Robert C. Courtney   《Earth and Planetary Science Letters》1987,83(1-4)

Heat flow in the Sohm abyssal plain is measured to be 53 mW/m² at an age of 163 Ma. This is 25% higher than predicted by conductive cooling models, even though the sediment-corrected basement depth of 6.5 km at this location is normal for its age. An analysis of existing heat flow, depth and geoid anomalies in the northwest Atlantic shows that there is little correlation between heat flow and depth throughout the entire region. Depth and geoid are clearly related to the Bermuda swell while the associated heat flow anomaly, once adjusted for variations with age, is limited to 5 mW/m² and only decays to the south. This means that the Bermuda swell is probably not caused by extensive thermal reheating within the lithosphere, but instead by dynamic uplift at its lower boundary due to the convective upwelling of a mantle plume. The regionally high heat flow in the northwest Atlantic may be a thermal remanent of previous plumes which passed beneath this region early in its history. Therefore, depth and heat flow anomalies from this region cannot be used to provide constraints on steady-state parameters of the lithosphere, such as the presence or absence of a long-term boundary layer at its base.  相似文献   

    

Wallace H. MacLean 《Contributions to Mineralogy and Petrology》2004,146(6):779

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Magma degassing and basaltic eruption styles: a case study of 2000 year BP Xitle volcano in central Mexico   总被引：1，自引：0，他引：1  

Pablo Cervantes  Paul Wallace   《Journal of Volcanology and Geothermal Research》2003,120(3-4):249-270

To investigate the relationship between volatile abundances and eruption style, we have analyzed major element and volatile (H₂O, CO₂, S) concentrations in olivine-hosted melt inclusions in tephra from the 2000 yr BP eruption of Xitle volcano in the central Trans-Mexican Volcanic Belt. The Xitle eruption was dominantly effusive, with fluid lava flows accounting for 95% of the total dense rock erupted material (1.1 km³). However, in addition to the initial, Strombolian, cinder cone-building phase, there was a later explosive phase that interrupted effusive activity and deposited three widespread ash fall layers. Major element compositions of olivine-hosted melt inclusions from these ash layers range from 52 to 58 wt.% SiO₂, and olivine host compositions are Fo_84–86. Water concentrations in the melt inclusions are variable (0.2–1.3 wt.% H₂O), with an average of 0.45±0.3 (1σ) wt.% H₂O. Sulfur concentrations vary from below detection (50 ppm) to 1000 ppm but are mostly ≤200 ppm and show little correlation with H₂O. Only the two inclusions with the highest H₂O have detectable CO₂ (310–340 ppm), indicating inclusion entrapment at higher pressures (700–900 bars) than for the other inclusions (≤80 bars). The low and variable H₂O and S contents of melt inclusions combined with the absence of less soluble CO₂ indicates shallow-level degassing before olivine crystallization and melt inclusion formation. Olivine morphologies are consistent with the interpretation that most crystallization occurred rapidly during near-surface H₂O loss. During cinder cone eruptions, the switch from initial explosive activity to effusive eruption probably occurs when the ascent velocity of magma becomes slow enough to allow near-complete degassing of magma at shallow depths within the cone as a result of buoyantly rising gas bubbles. This allows degassed lavas to flow laterally and exit near the base of the cone while gas escapes through bubbly magma in the uppermost part of the conduit just below the crater. The major element compositions of melt inclusions at Xitle show that the short-lived phase of renewed explosive activity was triggered by a magma recharge event, which could have increased overpressure in the storage reservoir beneath Xitle, leading to increased ascent velocities and decreased time available for degassing during ascent.  相似文献   

Ore textures within the U lens of the Navan Zn-Pb deposit, Ireland     

Wendy M. Peace  Malcom W. Wallace  Mark P. Holdstock  John H. Ashton 《Mineralium Deposita》2002,38(5):568-584

Recent exploration in the vicinity of the giant (>90 Mt) Navan orebody has resulted in the discovery of ore-grade mineralisation to the southwest of the deposit, much of which occurs within the Upper Pale Beds, a horizon that is only weakly mineralised above the main orebody. Within this new U lens, mineralisation preferentially occurs within bioclastic carbonate grainstones and calcareous quartz sandstones, and is dominated by sulphide replacement of the carbonate component of the host sequence. Much of the replacive mineralisation is spatially associated with hydrothermal cavities, which are filled by a variable mixture of brecciated replacement sulphide minerals, space-filling sulphide and gangue cements, and internal sediments. Mineralisation also occurs within veins and dissolution seams, and as disseminated sulphide minerals. Massive mineralisation is typically a complex, chaotic, combination of replacement, cavity, and fracture-filling sulphides. Fluid inclusion analyses of ore-stage saddle dolomite indicate temperatures at the time of sulphide precipitation of ~90–150 °C, with a maximum of 175 °C. These temperatures are lower than those typically proposed for Irish-type deposits.  相似文献   

Water resources and their use in food production systems     

Jim S. Wallace  Peter J. Gregory 《Aquatic Sciences - Research Across Boundaries》2002,64(4):363-375

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Precipitation interception in Australian tropical rainforests: II. Altitudinal gradients of cloud interception,stemflow, throughfall and interception     

David McJannet  Jim Wallace  Paul Reddell 《水文研究》2007,21(13):1703-1718

This article presents a comprehensive study of canopy interception in six rainforests in Australia's Wet Tropics for periods ranging between 2 and 3·5 years. Measurements of rainfall, throughfall, stemflow and cloud interception were made at sites characterized by different forest types, canopy structure, altitude, rainfall and exposure to prevailing winds. Throughfall at these sites ranged between 64 and 83% of total precipitation inputs, while stemflow ranged between 2 and 11%. At sites higher than 1000 m, cloud interception was found to contribute up to 66% of the monthly water input to the forest, more than twice the rainfall at these times. Over the entire study period, cloud interception accounted for between 4 and 30% of total precipitation inputs, and was related more to the exposure of sites to prevailing winds than to altitudinal differences alone. Over the duration of the study period, interception losses ranged between 22 and 29% of total water input (rainfall and cloud interception) at all sites except the highest altitude site on Bellenden Ker, where interception was 6% of total water input. This smaller interception loss was the result of extremely high rainfall, prolonged immersion in cloud and a sparser canopy. On a monthly basis, interception losses from the six sites varied between 10 and 88% of rainfall. All sites had much higher interception losses during the dry season than in the wet season because of the differences in storm size and rainfall intensity. The link between rainfall conditions and interception losses has important implications for how evaporative losses from forests may respond to altered rainfall regimes under climate change and/or large‐scale atmospheric circulation variations such as El Niño. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献